An efficient procedure for the preparation of chiral β-substituted (E)-crotylsilanes: Application of a rhodium(II) catalyzed silylformylation of terminal alkynes

DOI: 10.1016/0040-4039(95)01894-N

Source and publish data:

Tetrahedron Letters p. 8723 - 8726 (1995)

Update date:2022-08-05

Topics:

Authors:

Jain Jain

Jain, Nareshkumar F.

Cirillo Cirillo

Cirillo, Pier F.

Schaus Schaus

Schaus, Jennifer V.

Panek Panek

Panek, James S.

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Article abstract of DOI:10.1016/0040-4039(95)01894-N

Functionalized β-substituted (E)-crotylsilanes (R)-7 and (S)-8, bearing an alkyl or aryl group adjacent to the stereogenic C-Si center have been synthesized in an efficient four-step procedure initiated with a regio- and stereoselective silylformylation o

Full text of DOI:10.1016/0040-4039(95)01894-N

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