Sterically demanding aryloxides as supporting ligands in organoactinide chemistry. Synthesis, structural characterization, and reactivity of Th(O-2,6-t-Bu2C6H3)2(CH 2SiMe3)2 and

DOI: 10.1021/om950654u

Source and publish data:

Organometallics p. 949 - 957 (1996)

Update date:2022-08-04

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Authors:

Clark, David L.

Grumbine, Steven K.

Scott, Brian L.

Watkin, John G.

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Article abstract of DOI:10.1021/om950654u

Reaction of ThBr₄(THF)₄ with 2 equiv of KOAr (Ar = 2,6-t-Bu₂C₆H₃) produces the bis-(aryloxide) complex ThBr₂(OAr)₂(THF)₂ (1) in 67percent yield. Alkylation of 1 with 2

Full text of DOI:10.1021/om950654u

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