Journal of the Chemical Society, Dalton Transactions p. 291 - 298 (1996)
Update date:2022-08-04
Topics:
Hiraki, Katsuma
Kinoshita, Yuji
Kinoshita-Kawashima, Junko
Kawano, Hiroyuki
The hydridoruthenium(II) complex [RuCl(H)(CO)(PPh3)3] 1 reacted with aromatic nitriles at 120°C in the presence of water to give novel N-imidoylimidatoruthenium(II) complexes [RuCl(NH=CRN=CRO)(CO)(PPh3)2] (R = C6H4Me-p 2, Ph 3, or C6H4Me-m 4). In contrast, reaction of o-toluonitrile with 1 gave a small amount of the corresponding N-imidoylimidato complex and a considerable amount of o-toluamide. When 1 was heated at 120°C in a 1:1 mixture of an amide R1CONH2 and a nitrile R2CN a cross-linked N-imidoylimidato complex [RuCl(NH=CR2N=CR1O)(CO)(PPh3)2] 6 (R1 = Ph, R2 = C6H4Me-p) or 7 (R1 = C6H4Me-p, R2 = Ph) was obtained. Single-crystal structure analyses of 2 and 6 have been performed.
Changsha Goomoo Chemical Technology Co.Ltd
Contact:+86-731-82197655
Address:No.649,Chezhan Rd.(N),Changsha,Hunan,China
Weifang Arylchem Chemical Co., LTD
Contact:86-536-5217866
Address:Development Zone, Shouguang, Shandong Province
Jiangxi Hito Chemical Co., Ltd.
Contact:+86-792-3170318
Address:No. 6, Tianhong Ave., Xinghuo Industry Park, Yongxiu, Jiujiang, Jiangxi, China
PharmaResources(Kaiyuan)CO,.Ltd
Contact:+86-21-50720028
Address:No.3, Beihuan Road, Economic Development District, Kaiyuan City, Tieling City, Liaoning Province, China 112300
Hefei Highzone Fine Chemical S&T CO.,LTD
Contact:86-0551-63663560
Address:room 1801 NO. 24 Shuguang RD.
Doi:10.1021/ja00347a041
(1983)Doi:10.1021/ja0318479
(2004)Doi:10.1021/ol050119i
(2005)Doi:10.1021/ic048615a
(2005)Doi:10.1055/s-2004-837223
(2005)Doi:10.1055/s-2005-862376
(2005)
