Journal of the Chemical Society, Dalton Transactions p. 291 - 298 (1996)
Update date:2022-08-04
Topics:
Hiraki, Katsuma
Kinoshita, Yuji
Kinoshita-Kawashima, Junko
Kawano, Hiroyuki
The hydridoruthenium(II) complex [RuCl(H)(CO)(PPh3)3] 1 reacted with aromatic nitriles at 120°C in the presence of water to give novel N-imidoylimidatoruthenium(II) complexes [RuCl(NH=CRN=CRO)(CO)(PPh3)2] (R = C6H4Me-p 2, Ph 3, or C6H4Me-m 4). In contrast, reaction of o-toluonitrile with 1 gave a small amount of the corresponding N-imidoylimidato complex and a considerable amount of o-toluamide. When 1 was heated at 120°C in a 1:1 mixture of an amide R1CONH2 and a nitrile R2CN a cross-linked N-imidoylimidato complex [RuCl(NH=CR2N=CR1O)(CO)(PPh3)2] 6 (R1 = Ph, R2 = C6H4Me-p) or 7 (R1 = C6H4Me-p, R2 = Ph) was obtained. Single-crystal structure analyses of 2 and 6 have been performed.
Contact:+86-913-2223392
Address:No. 32, Xinanjing Road, Weinan City, Shaanxi Province, 714000, China
Taizhou volsen chemical Co., Ltd
website:http://www.volsenchem.com
Contact:+86-576-88869393
Address:Jiaojiang District, Taizhou, Zhejiang, China.
Contact:86-10-62664360
Address:Building 10,No.18 AnNingZhuang East Road, GuangHua Pioneer Park,HaiDian District, BeiJing China
Contact:886 2 2541 0022
Address:8 Fl., No. 11, Sec. 1, Chung Shan North Rd., Taipei, Taiwan R.O.C.
Meryer (Shanghai) Chemical Technology Co., Ltd.
website:http://www.meryer.com/cn/index/
Contact:+86-755-86170518
Address:Minhang,Shanghai, China
Doi:10.1021/ja00347a041
(1983)Doi:10.1021/ja0318479
(2004)Doi:10.1021/ol050119i
(2005)Doi:10.1021/ic048615a
(2005)Doi:10.1055/s-2004-837223
(2005)Doi:10.1055/s-2005-862376
(2005)
