Journal of the Chemical Society. Chemical communications p. 197 - 198 (1980)
Update date:2022-08-02
Cookson, Richard C.
Cramp, Michael C.
Parsons, Philip J.
While the prop-2-ynyl acetates (1) rearrange to the allenyl acetates (2) in boiling benzene containing copper(I) chloride, in the presence of silver trifluoroacetate the butadienyl acetates (3), useful in Diels-Alder reactions, are formed in high yield.
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