Lewis acid catalyzed Diels-Alder reaction of 3-phenylthio-2-quinolinones with siloxydiene. Synthesis of the intermediate for dynemicin A core

DOI: 10.1248/cpb.44.451

Source and publish data:

Chemical and Pharmaceutical Bulletin p. 451 - 453 (1996)

Update date:2022-08-05

Topics:

Authors:

Nagata Nagata

Koide Koide

Nara Nara

Itoh Itoh

Arisawa Arisawa

Naruto Naruto

Torisawa

Hino Hino

Nakagawa

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Article abstract of DOI:10.1248/cpb.44.451

Preparation of the 1-methoxycarbonyl-3-phenylthio-2-quinolinone (10) from dihydro-2-quinolinone (5) and its Diels-Alder reaction with 2- trimethylsilyloxy-1,3-butadiene under Lewis acid catalyst is described. Conversion of the D-A adduct (11) to 9-phenant

Full text of DOI:10.1248/cpb.44.451

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