Simple synthesis of 2H-1,3-oxazines and their stereoselective transformation into 1,3-aminoalcohols and azetidines

DOI: 10.1016/0040-4020(95)01097-1

Source and publish data:

Tetrahedron p. 3095 - 3106 (1996)

Update date:2022-08-04

Topics:

Authors:

Barluenga, Jose

Tomas, Miguel

Ballesteros, Alfrede

Kong, Jian-She

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/0040-4020(95)01097-1

4-Amino-1-azadienes 1 undergo cyclization at 20-50°C with esters of glyoxylic acid giving rise to 2H-1,3-oxazines 3. These compounds are reduced with NaBH₃CN/AcOH affording stereoselectivity syn, syn-1,3-aminoalcohols 4, which are further O-mes

Full text of DOI:10.1016/0040-4020(95)01097-1

Products guided by the article

Product name:2-ethoxycarbonyl-4-(2-furyl)-6-(4-methoxyphenyl)-5-methyl-2H-1,3-oxazine

Cas No:175727-87-4

R&D Labs maybe for 175727-87-4

enantiotech corporation ltd

Contact:+86-0760-85282375

Address:zhongjing road,zhongshan torch hi-tech industrial development zone
SINFACHEM LIMITED

Contact:86-25-84683399

Address:605, Phoenix Herui Plaza, No.389, South Taiping Road, Nanjing, China 210002
Baicao Pharmaceutical Co., Ltd.

website:http://www.jxbaicao.com

Contact:+86-796-8113329

Address:It (country) economic and technological development zone of the jinggang mountains
Luna Chemicals Co.,Ltd.

Contact:+86-570-4336358

Address:No.87 Building,Tianqian,Sidu Town
LinHai Cina Chemical Co., LTD.

Contact:0576-85580989

Address:Pharma-chem zone,Duqiao,Linhai,Zhejiang,China

Relevant to this article

Homo- and hetero-bridged mixed-valence dinuclear complexes which contain the fragment 'Rh(C₆F₅)₃'

Doi:10.1016/0022-328X(95)05884-R
(1996)
Chemical synthesis, DNA cleavage and antitumor activity of molecules with (Z)-7-sulfonyl-3-hexene-1,5-diyne functionalities

Doi:10.1016/0960-894X(96)00090-X
(1996)
5(N-methylbenzoylamino)-2,2,6,6-tetramethylheptan-3-ol as a new class of recoverable chiral auxiliary

Doi:10.1016/0040-4039(96)00137-2
(1996)
Alumoxanes as cocatalysts in the palladium-catalyzed copolymerization of carbon monoxide and ethylene: Genesis of a structure-activity relationship

Doi:10.1021/om9508492
(1996)
Doi:10.1021/ja01178a080
(1949)
Alkylation of oxiranyl anions

Doi:10.1016/0040-4039(96)00381-4
(1996)

Article Doi