Effect of alkali cations on the methoxide ion addition to corands incorporating a thiopyrylium subunit

DOI: 10.1016/0040-4020(96)00029-4

Source and publish data:

Tetrahedron p. 3509 - 3520 (1996)

Update date:2022-08-03

Topics:

Authors:

Doddi, Giancarlo

Fazio, Maria Cristina

Luvidi, Loredana

Mencarelli, Paolo

Ercolani, Gianfranco

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Article abstract of DOI:10.1016/0040-4020(96)00029-4

The incorporation of a thiopyrylium ring in a corand structure forms a system with a weak binding ability in methanol towards the alkali cations K⁺, Rb⁺ and Cs⁺. The binding substantially increases in basic solution becaus

Full text of DOI:10.1016/0040-4020(96)00029-4

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