Radical additions to olefins in the presence of iodobenzenediacetate: An easy route to alkyl dithiocyanates

DOI: 10.1016/0040-4039(96)00144-X

Source and publish data:

Tetrahedron Letters p. 1889 - 1892 (1996)

Update date:2022-07-31

Topics:

Authors:

De Mico, Antonella

Margarita, Roberto

Mariani, Andrea

Piancatelli, Giovanni

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/0040-4039(96)00144-X

We describe a new application of iodobenzenediacetate (IBDA), which is able to oxidize thiocyanate anion to the corresponding radical. Subsequent addition to nucleophilic olefins leads to dithiocyanate derivatives. The radical addition to olefins is more effective when performing the thiocyanation reaction in presence of Mg(ClO₄)₂ or TEMPO.

Full text of DOI:10.1016/0040-4039(96)00144-X

Products guided by the article

Product name:(1R,2S)-1,2-Bis-thiocyanato-cyclohexane

Cas No:176214-67-8

R&D Labs maybe for 176214-67-8

Shifang Taifeng New Flame Retardant Co., Ltd

Contact:02884721008

Address:tingjiang industrial park, hefeng town
Shenzhen ZheYi Chemicals Co.,LTD(Shanghai Branch)

Contact:+86-21-54159691

Address:Room1002,Building No.2, Lane 98 Bixiu Road,Minhang District, Shanghai,China 201100
Beijing Greenchem Technology Co.,Ltd. ( Panjin Greenchem Technology Co.Ltd .)

website:http://www.bjgreenchem.com/

Contact:+86-427-6515887

Address:301,302, 3rd Floor, Building C-7, Dongsheng Science Park, Northern Territory, Zhongguancun, No. 66, Xixiaokou Road, Haidian District, Beijing
Qida Chemical Co., Ltd.(expird)

Contact:+86-25-8776 0031

Address:3-2001 Jiaye Int'l Town, 158 Lushan Road,Nanjing, 210019, China
Zhuhai Rundu Pharmaceutical co.,Ltd

Contact:+86-756-7630755

Address:No.6,North Airport Road,Sanzao Town,Jinwan District

Relevant to this article

Poststatin, a new inhibitor of prolyl endopeptidase - III. Optical resolution of 3-amino-2-hydroxyvaleric acid and absolute configuration of poststatin

Doi:10.7164/antibiotics.49.281
(1996)
Total synthesis of (±)-lennoxamine and (±)-aphanorphine by intramolecular electrophilic aromatic substitution reactions of 2-amidoacroleins

Doi:10.1021/ol016795b
(2001)
Saccharide control of energy-transfer luminescence of lanthanide ions encapsulated in calix[4]arenes: A novel discrimination method for the energy-transfer route

Doi:10.1246/cl.1996.301
(1996)
Synthesis of enantiomerically pure trans aziridine-2-carboxylates by diastereoselective Gabriel-Cromwell reaction

Doi:10.1016/0957-4166(96)00071-7
(1996)
Synthesis of Bestatin, a Potent Inhibitor of Leukotriene A4 Hydrolase, by an N₃ Nucleophile Reaction to a Non-protected Diol

Doi:10.1271/bbb.60.534
(1996)
Doi:10.1021/ja01078a061
(1964)

Article Doi