Radical additions to olefins in the presence of iodobenzenediacetate: An easy route to alkyl dithiocyanates

DOI: 10.1016/0040-4039(96)00144-X

Source and publish data:

Tetrahedron Letters p. 1889 - 1892 (1996)

Update date:2022-07-31

Topics:

Authors:

De Mico, Antonella

Margarita, Roberto

Mariani, Andrea

Piancatelli, Giovanni

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Article abstract of DOI:10.1016/0040-4039(96)00144-X

We describe a new application of iodobenzenediacetate (IBDA), which is able to oxidize thiocyanate anion to the corresponding radical. Subsequent addition to nucleophilic olefins leads to dithiocyanate derivatives. The radical addition to olefins is more effective when performing the thiocyanation reaction in presence of Mg(ClO₄)₂ or TEMPO.

Full text of DOI:10.1016/0040-4039(96)00144-X

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