Journal of the Chemical Society, Dalton Transactions p. 969 - 973 (1996)
Update date:2022-09-26
Topics:
Ruiz, Nuria
Castillon, Sergio
Ruiz, Aurora
Claver, Carmen
Aaliti, Abdellatif
Alvarez-Larena, Angel
Piniella, Joan F.
Germain, Gabriel
The addition of the atropisomeric racemic sulfur compound 1,1′-binaphthalene-2,2′-dithiol (H2L) to a dichloromethane solution of [{Rh(μ-OMe)(cod)}2] (cod = cycloocta-1,5-diene) afforded the dithiolate-bridged complexes [{Rh2(μ-L)(cod)2}n] (n = 2 1 or 1 2). These reacted with carbon monoxide to give the dinuclear tetracarbonyl complex [Rh2(μ-L)(CO)4] 3. The reaction of 3 with PR3 provided the mixed-ligand complexes [{Rh2(μ-L)(CO)2(PR3)2} 2] (R = Ph 4 or C6H11 5) and [{Rh2(μ-L)(CO)3(PR3)}2] 6 [R = P(OC6H4But-o)3]. The crystal structure of 6 was determined by X-ray diffraction.
Puyang Huicheng Electronic Material Co., Ltd
website:http://huichengchem.weba.testwebsite.cn/index_en.html
Contact:+86-393-8910800
Address:West Section Shengli Road, Puyang457000, China
Contact:+86-710-3516804
Address:Number 83,Panggong road,Xiangcheng District,Xiangyang ,Hubei
Global United Biotechnology Inc.
Contact:+86-21-61618568
Address:Room 309, Building 6, NO.135, Jinyu Road, Pudong
Taizhou Huading Chemical Co.,Ltd(expird)
Contact:+86-576-88583898
Address:Economic&Technology development zone,Taizhou City,Zhejiang Province,China
YingYing Pharmaceutical Co.,Ltd
Contact:86-18854126208
Address:55#, yingxiongshan road
Doi:10.1002/anie.201304143
(2013)Doi:10.1016/0040-4020(96)00229-3
(1996)Doi:10.1016/0040-4020(96)00217-7
(1996)Doi:10.1081/SCC-120003629
(2002)Doi:10.1021/ja00742a017
(1971)Doi:10.1039/CC9960001199
(1996)
