Study of the complexing properties toward RuII of new polydentate amphiphilic phosphines containing polyether chains. Unprecedented η3 mode of bonding of the new ligand PPh[(CH2)3CHMe2][(CH2CH 2O)3Me] and study of its hemilabile character

DOI: 10.1039/CC9960000771

Source and publish data:

Chemical Communications p. 771 - 772 (1996)

Update date:2022-08-03

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Authors:

Valls, Esteve

Suades, Joan

Donadieu, Bruno

Mathieu, Rene

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Article abstract of DOI:10.1039/CC9960000771

New polydentate amphiphilic phosphines containing polyether chains are prepared; unprecedented coordination and reactivity of the hemilabile ligand PPh[(CH₂)₃CHMe₂][(CH₂CH ₂O)₃Me] are found; the η³ mode of bonding of this ligand is demonstrated by X-ray crystallographic studies.

Full text of DOI:10.1039/CC9960000771

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