A new stereoselective synthesis of chiral γ-functionalized (E)-allylic amines

DOI: 10.1016/0040-4020(96)00617-5

Source and publish data:

Tetrahedron p. 10985 - 10996 (1996)

Update date:2022-08-03

Topics:

Authors:

Reginato, Gianna

Mordini, Alessandro

Messina, Flavia

Degl'Innocenti, Alessandro

Poli, Giovanni

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/0040-4020(96)00617-5

Chiral t-Boc protected propargylic amines have been obtained starting from aminoaldehydes derived from natural aminoacids. Stannylcupration of these substrates affords an easy regio- and stereocontrolled route to the corresponding γ-stannylated (E)-allylamines which are useful intermediates for the synthesis of the corresponding γ-functionalized allylic systems.

Full text of DOI:10.1016/0040-4020(96)00617-5

Products guided by the article

Product name:((S)-3,3-Dibromo-1-methyl-allyl)-carbamic acid tert-butyl ester

Cas No:176962-17-7

R&D Labs maybe for 176962-17-7

Hubei Xinghuo Chemical Co., Ltd.,

Contact:13925817279 13907299441

Address:Xinghuo Fine Chemistry Industrial Park, Xiaochang County, Hubei Province, China
Yuan Shi(SuQian)Biotechnology Co.,Ltd

website:http://www.yuanshibio.com

Contact:+86-527-84226672

Address:jiangsu suqian
Deer Chemicals Co., Ltd.

Contact:+86-13666670345

Address:Agricultural Development Zone, Haining, Jiaxing, Zhejiang
SINO Industries Company Limited(expird)

Contact:86-29-85369724

Address:No.111, Jiefang Road, Xi’an, China
Shanghai Hohance Chemical Co., ltd

Contact:13914753421

Address:Fl.5；Bld. 70, Lane 1500; Xinfei Road

Relevant to this article

Fluorescent ethenyl- and ethynyl-dimesitylboranes derived from 5-(dimethylamino)-N-(prop-2-ynyl)naphthalene-1-sulfonamide

Doi:10.1071/CH07242
(2007)
Pd(II)-catalyzed enantioselective intramolecular oxidative amination utilizing (+)-camphorsulfonic acid

Doi:10.1016/j.tetlet.2017.07.090
(2017)
Synthesis and reactions of N,N-bis[1-(trimethylsiloxy)alkyl]-formamides: Preparation of (±)-argemonine and (±)-norargemonine

Doi:10.1039/P19960000907
(1996)
Annulation of heterocyclic rings on aromatic templates: The quinone monoketal route

Doi:10.1016/0040-4039(96)00424-8
(1996)
S,S-dimethyl dithiocarbonate: A convenient reagent for the synthesis of symmetrical and unsymmetrical ureas

Doi:10.1021/jo9522825
(1996)
Structure-activity relationships of 1-alkyl-5-(3,4-dichlorophenyl)-5-{2-[(3-substituted)-1-azetidinyl]ethyl} -2-piperidones. 1. Selective antagonists of the neurokinin-2 receptor

Doi:10.1021/jm0209331
(2002)

Article Doi