A new stereoselective synthesis of chiral γ-functionalized (E)-allylic amines

DOI: 10.1016/0040-4020(96)00617-5

Source and publish data:

Tetrahedron p. 10985 - 10996 (1996)

Update date:2022-08-03

Topics:

Authors:

Reginato, Gianna

Mordini, Alessandro

Messina, Flavia

Degl'Innocenti, Alessandro

Poli, Giovanni

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Article abstract of DOI:10.1016/0040-4020(96)00617-5

Chiral t-Boc protected propargylic amines have been obtained starting from aminoaldehydes derived from natural aminoacids. Stannylcupration of these substrates affords an easy regio- and stereocontrolled route to the corresponding γ-stannylated (E)-allylamines which are useful intermediates for the synthesis of the corresponding γ-functionalized allylic systems.

Full text of DOI:10.1016/0040-4020(96)00617-5

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Product name:((S)-3,3-Dibromo-1-methyl-allyl)-carbamic acid tert-butyl ester

Cas No:176962-17-7

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