Tetrahedron p. 10985 - 10996 (1996)
Update date:2022-08-03
Topics:
Reginato, Gianna
Mordini, Alessandro
Messina, Flavia
Degl'Innocenti, Alessandro
Poli, Giovanni
Chiral t-Boc protected propargylic amines have been obtained starting from aminoaldehydes derived from natural aminoacids. Stannylcupration of these substrates affords an easy regio- and stereocontrolled route to the corresponding γ-stannylated (E)-allylamines which are useful intermediates for the synthesis of the corresponding γ-functionalized allylic systems.
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