A simple route to enantiopure fluorocyclohexenones

DOI: 10.1055/s-1996-4217

Source and publish data:

Synthesis p. 357 - 360 (1996)

Update date:2022-09-26

Topics:

Authors:

Weinmann, Hilmar

Winterfeldt, Ekkehard

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Article abstract of DOI:10.1055/s-1996-4217

The 4-fluoro substituted cyclohexadienone 10 was shown to undergo a very efficient differentiation of enantiotopic double bonds in a Diels-Alder cycloaddition process. Epoxidation followed by thermal retro reaction generated the enantiopure fluorocyclohex

Full text of DOI:10.1055/s-1996-4217

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Product name:(4S*,4aS*,4bS*,8aS*,9aR*)-4-fluoro-9-(4-methoxyphenyl)-4,8a-dimethyl-4b,5,6,7,8,9a-hexahydro-4b,9-etheno-4bH-fluoren-1(4H)-one

Cas No:177083-16-8

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