Alkylation of cyanide at [NBu4]trans-[Re(CN) 2(Ph2PCH2CH2PPh2) 2]. Syntheses and properties of derived isocyanide complexes and X-ray structure of trans-[Re(CNEt) 2(Ph2PCH2CH2PPh2) 2][PF6]

DOI: 10.1016/0022-328X(95)05956-P

Source and publish data:

Journal of Organometallic Chemistry p. 163 - 169 (1996)

Update date:2022-09-26

Topics:

Authors:

Carvalho, M. Fernanda N. N.

Duarte, M. Teresa

Galvao, Adelino M.

Pombeiro, Armando J. L.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/0022-328X(95)05956-P

The reaction of RI (R = Me, Et or Pr) or [Et₃O][PF₆] with [NBu₄]trans-[Re(CN)₂(dppe)₂] (dppe = Ph₂PCH₂CH₂PPh₂) affords the diisocyanide complexes trans-[Re(CNR)₂(dppe)₂]A (R = Me, A = I; R = Pr, A = I₃; R = Et, A = PF₆), whereas trans-[Re(CNH)(CNSiMe₃)(dppe)₂]CF₃SO₃ is obtained from the reaction with Me₃SiO₃SCF₃. The X-ray crystal structure of trans-[Re(CNEt)₂(dppe)₂][PF₆] was determined. The redox properties of the compounds were studied by cyclic voltammetry and controlled potential electrolysis, and are discussed in terms of the electronic properties of the metal centres and ligands.

Full text of DOI:10.1016/0022-328X(95)05956-P

Products guided by the article

Product name:trans-[ReI(CNPr)(dppe)2]

Cas No:177216-99-8

R&D Labs maybe for 177216-99-8

Anhui Xinyuan Technology Co.,Ltd

Contact:0086-559-3515800

Address:No.16 Zijin Rd, Circular Economic Zone, Huizhou District, Huangshan Anhui China
Brichem ( Haikou ) Co. Ltd.

Contact:86-898-65311214

Address:Room 102, BLDG. 68 Jiangnan City, No. 66 Heping Road,Haikou, Hainan, China
Beijing Chemdow Co., Ltd

website:http://www.chemdow.com

Contact:0086-10-82435335

Address:Room 401,Unit 3,4th Floor,Shangdijiayuan,Shangdi East Road, Haidian District,Beijing
BioBioPha Co., Ltd

Contact:+86-871-65217109

Address:132 Lanhei Road, Kunming Institute of Botany, Chinese Academy of Sciences
Haitong Chemical Industrial Co.,Ltd.

website:https://www.haitonglongwin.com/

Contact:+86-022-66221018

Address:18-701, No.99, The 4th Street, TEDA,

Relevant to this article

Reactions of di- and tri-nuclear palladium and platinum isocyanide complexes with highly basic and bulky aromatic phosphines containing methoxy groups at the 2 and 6 positions

Doi:10.1039/dt9960001815
(1996)
Facile oxidative hydrolysis of acetals to esters using hypervalent iodine(III)/LiBr combination in water

Doi:10.1016/j.tet.2010.01.098
(2010)
Doi:10.1021/ja00993a054
(1967)
Reactions of a triosmium cluster complex with a side-on- coordinated carbene ligand with sulfur compounds resulting in the formation of a thioketone complex

Doi:10.1002/anie.199609931
(1996)
Synthesis of conformationally restricted analogues of the tryptophanyl tRNA synthetase inhibitor indolmycin

Doi:10.1016/0040-4039(96)00471-6
(1996)
Optical control of AMPA receptors using a photoswitchable quinoxaline-2,3-dione antagonist

Doi:10.1039/C6SC01621A
(2016)

Article Doi