Asymmetric synthesis of (R)-sulcatol

DOI: 10.1016/0957-4166(96)00103-6

Source and publish data:

Tetrahedron Asymmetry p. 1005 - 1006 (1996)

Update date:2022-08-04

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Authors:

Davies, Stephen G.

Smyth, G. Darren

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Article abstract of DOI:10.1016/0957-4166(96)00103-6

The insect pheromone (R)-sulcatol, 2-hydroxy-6-methylhept-5-ene, is synthesized via a stereoselective conjugate addition of (R)-lithium N,α-dimethylbenzylamide to tert-butyl (E,E)-hexa-2,4-dienoate, Grignard addition, and stereospecific Meisenheimer rearr

Full text of DOI:10.1016/0957-4166(96)00103-6

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Product name:(3S,αR)-(E)-Methyl 3-hex-4-enoate

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