Tetrahedron Asymmetry p. 985 - 988 (1996)
Update date:2022-07-31
Topics:
Lucet, Denis
Le Gall, Thierry
Mioskowski, Charles
Ploux, Olivier
Marquet, Andree
A short and efficient synthesis of both 8-amino-7-oxopelargonic acid enantiomers from D or L-alanine is presented. The key step of this first chemical synthesis is the non-racemizing Horner-Wadsworth-Emmons reaction of a β-ketophosphonate 3 and benzyl 4-formylbutanoate. The growth promoting effect of the enantiomers was tested on Saccharomyces cerevisiae.
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(1967)
