Journal of the Chemical Society. Perkin transactions I p. 803 - 808 (1996)
Update date:2022-08-03
Topics:
Kim, Dae-Kee
Kim, Ganghyeok
Kim, Young-Woo
A new method for the preparation of optically active 3-substituted 1-benzylpiperidines based on the ring expansion of the 1-benzyl-2-(methylsulfonyloxymethyl)pyrrolidine 13 with various nucleophiles has been described. Synthesis of 4-amino-1,4,5-trideoxy-1,5-imino-D-ribitol 5, 1,4,5-trideoxy-4-fluoro-1,5-imino-D-ribitol 6 and 1,5-dideoxy-1,5-imino-D-ribitol 7 has also been achieved by a route which involves ring expansion of compound 13.
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Doi:10.1016/0957-4166(96)00172-3
(1996)Doi:10.1021/jo9618482
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