Organometallics p. 201 - 204 (1984)
Update date:2022-09-26
Topics:
Bricker, Jeffery C.
Bhattacharyya, Nripendra
Shore, Sheldon G.
Stoichiometries and conditions for the condensation of [HM(CO)4]- to [HM3(CO)11]- for M = Fe, Ru, and Os have been determined. Under protic and water gas shift conditions, the [HRu(CO)4]- anion is rapidly converted to the trinuclear cluster anion [HRu3(CO)11-]. In protic media the [HFe(CO)4]- anion condenses to [HFe3(CO)11]-, but at a markedly slower rate. Under water gas shift conditions, [HFe(CO)4]- does not form ([HFe3(CO)11]-. Instead, within a period of 24 h a catalytically inactive material is formed. In protic media [HOs(CO)4]- slowly forms [HOs3(CO)11]-. The [HOs(CO)4]- anion is more active than [HOs3(CO)11]- for the catalysis of the water gas shift reaction.
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