Organometallics p. 201 - 204 (1984)
Update date:2022-09-26
Topics:
Bricker, Jeffery C.
Bhattacharyya, Nripendra
Shore, Sheldon G.
Stoichiometries and conditions for the condensation of [HM(CO)4]- to [HM3(CO)11]- for M = Fe, Ru, and Os have been determined. Under protic and water gas shift conditions, the [HRu(CO)4]- anion is rapidly converted to the trinuclear cluster anion [HRu3(CO)11-]. In protic media the [HFe(CO)4]- anion condenses to [HFe3(CO)11]-, but at a markedly slower rate. Under water gas shift conditions, [HFe(CO)4]- does not form ([HFe3(CO)11]-. Instead, within a period of 24 h a catalytically inactive material is formed. In protic media [HOs(CO)4]- slowly forms [HOs3(CO)11]-. The [HOs(CO)4]- anion is more active than [HOs3(CO)11]- for the catalysis of the water gas shift reaction.
ZHEJIANG PAULA INDUSTRY CO.,LTD
website:http://www.haiqiangchem.com
Contact:86-571-86960380
Address:6th floor, building 2, dongfangmao business center, Xiacheng District, Hangzhou City, Zhejiang Province
Contact:86-551-63540590
Address:No 1388 Furong Rd., Hefei, Anhui, China
Contact:+86-21-38122007
Address:2, Lane 1123, Kangqiao Road, Pudong New Area, Shanghai
Beijing Greenchem Technology Co.,Ltd. ( Panjin Greenchem Technology Co.Ltd .)
website:http://www.bjgreenchem.com/
Contact:+86-427-6515887
Address:301,302, 3rd Floor, Building C-7, Dongsheng Science Park, Northern Territory, Zhongguancun, No. 66, Xixiaokou Road, Haidian District, Beijing
jiangsu senxuan pharmaceutical and chemical co.,ltd
Contact:86-523-87982810
Address:hongqiao industrial zone,taixing,jiangsu china
Doi:10.1016/S0040-4039(00)97181-8
(1990)Doi:10.1016/0040-4039(96)00820-9
(1996)Doi:10.1021/jm00307a023
(1968)Doi:10.1016/0022-328X(68)80009-9
(1968)Doi:10.1006/bioo.1996.0015
(1996)Doi:10.1016/0022-328X(96)06221-3
(1996)
