Journal of the Chemical Society, Dalton Transactions p. 2269 - 2273 (1996)
Update date:2022-08-04
Topics:
Siasios, George
Tiekink, Edward R. T.
The square-planar nickel(II) complexes [Ni{Ph2PC(S)NPh}2] and [Ni{Ph2P(Y)C(S)NPh}2] (Y = S or Se) have been prepared and characterised spectroscopically. Their structures have been confirmed by single-crystal X-ray diffraction methods. In [Ni{Ph2PC(S)NPh}2] the Ni atom is chelated by the thioamide S atoms [2.188(2), 2.163(2) A] and phosphine P atoms [2.171(2), 2.182(2) A] which define a trans-S2P2 donor set. In [Ni{Ph2P(S)C(S)NPh}2] the centrosymmetric structure features S,S chelating ligands with the Ni-S (thioamide) distance of 2.184(2) A being equivalent to the Ni-S (sulfide) distance of 2.197(2) A in the S4 donor set. In [Ni{Ph2P(Se)C(S)NPh}2] the Ni atom in the centrosymmetric structure exists in a square-planar S2Se2 donor set with Ni-S 2.202(3) A and Ni-Se 2.344(1) A.
Tianjin Realet Chemical Technology Co.,Ltd.
website:http://www.realetchem.com
Contact:+86-022-58788819
Address:shuanggang industrial park
Contact:+86-021-50792271
Address:Building 24A, 300 Chuantu Road, Chuansha, Pudong new area, Shanghai, China, 201202
Hunan Shineway Enterprise Co., Ltd.
Contact:+86-731-86303875
Address:118, Huanghua International Airport Road, Huanghua Town, Changsha, Hunan 410137, China
Zhejiang Chemline International Co., Ltd.
Contact:+86-571-88062298
Address:Hengdian Industry Area, Dongyang, Zhejiang, China
Chengdu Green technology Co.,Ltd.
Contact:86-28-82608355
Address:C9 ,Economic Headquarters, Economic Development Zone, Chengdu.
Doi:10.1016/0020-1693(95)04813-8
(1996)Doi:10.1007/BF00853707
()Doi:10.1007/s11426-012-4605-y
(2012)Doi:10.1039/dt9960002449
(1996)Doi:10.1016/j.tetlet.2004.04.085
(2004)Doi:10.1002/zaac.19966220710
(1996)
