Bioorganic and Medicinal Chemistry Letters p. 1461 - 1464 (1996)
Update date:2022-07-31
Topics:
Chung, Sung-Kee
Yu, Seok-Ho
The Ferrier rearrangement of a methyl α-D-mannopyranoside derivative (8a), followed by a stereoselective reduction gave a L-chiro-inositol derivative (2), which was converted to L-chiro-inositol 1,2,3-trisphosphate (3) and L-chiro-inositol 1,2,3,5-tetxakisphosphate (4). Compounds 3 and 4 may be considered to be the C3-position stereoisomers of D-myo-inositol 1,2,6- trisphosphate (α-trinositol) and D-myo-inositol 1,3,4,5-tetrakisphosphate, respectively, and should be useful for the binding studies with their macromolecular counterparts.
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