Inorganic Chemistry p. 1761 - 1765 (1967)
Update date:2022-08-03
Topics:
Gilje, John W.
Morse, Karen W.
Parry
The compound of empirical composition B2H6·PH3·NH3, formed by the reaction of ammonia with H3BPH3, has the structure [NH4] +[H2P(BH3)2]-. The structure is conclusively supported by chemical evidence, by 1H, 11B, and 31P nmr spectra, and by infrared spectra. In terms of a useful analogy relating the isoelectronic BH3 group and an O atom as ligands, the compound [NH4] [H2P(BH3)2] is the BH3 analog of ammonium hypophosphite, [NH4] [H2PO2]. Copyright 1967 by the American Chemical Society.
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