Mixed-ligand platinum(II) complexes of [N(SPR2)2]- (R = Ph, OPh)

DOI: 10.1016/0277-5387(96)00054-X

Source and publish data:

Polyhedron p. 3175 - 3181 (1996)

Update date:2022-08-03

Topics:

Authors:

Williams, David J.

Slawin, Alexandra M. Z.

Phillips, Julian R.

Woollins, J. Derek

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Article abstract of DOI:10.1016/0277-5387(96)00054-X

The preparation of complexes of the type {Pt(R₃P)₂[(SPR₂),N]} X (R = Ph, OPh, X = Cl^-, PF^-₆) and {Pt(PR₃)[N(SPR₂)₂]Cl} is described. The new complexes have been characterized by NMR and IR, microanaiyses and in the case of {Pt(PPh₃)[N(SPPh₂)₂]Cl} by X-ray crystallography. The PtS₂P₂N ring adopts a pseudo-boat conformation. Copyright

Full text of DOI:10.1016/0277-5387(96)00054-X

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