The thermally induced synthesis of N-(diethoxyphosphoryl)aldimines

Article abstract of DOI:10.1016/0040-4020(96)00420-6

The reaction of diethyl phosphoroamidate (2) with aromatic aldehyde diethyl acetals (1) carried out at 120-160°C provides a simple, one-step preparation of N-(diethoxyphosphoryl)aldimines (3a-b). The extension of this reaction to aliphatic aldehyde diethyl acetals failed to give the expected imines.