Substituent-dependent asymmetric synthesis of L-threo- and L-erythro-[2,3-2H2]phenylalanine from chiral (Z)-dehydrophenylalanine

DOI: 10.1039/cc9960001875

Source and publish data:

Chemical Communications p. 1875 - 1876 (1996)

Update date:2022-08-04

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Authors:

Oba, Makoto

Nakajima, Shinji

Nishiyama, Kozaburo

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Article abstract of DOI:10.1039/cc9960001875

A stereo-divergent synthesis of L-threo- and L-erythro-[2,3-²H₂]-phenylalanine by a catalytic deuteriation of (Z)-dehydrophenylalanine included in a chiral diketopiperazine ring is accomplished simply by changing the substituents on the nitrogen atoms in the diketopiperazine ring.

Full text of DOI:10.1039/cc9960001875

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