Chemical Communications p. 1563 - 1564 (1996)
Update date:2022-09-26
Topics:
Green, Melinda J.
Britovsek, George J. P.
Cavell, Kingsley J.
Skelton, Brian W.
White, Allan H.
From the catalytic conversion of CO and ethene to polyketone with [Pd(Me)(NC5H4CO2Me-2)- (PPh3)]BF4 1, the reaction of ethene with [Pd(COMe)(NC5H4CO2Me-2)-(PPh 3)]BF4 2 yields a rare example of an isolable product from the insertion of an unstrained alkene into a Pd-acyl bond, and the crystal structure of [Pd(CH2CH2COMe)-(NC5H4CO 2Me-2)(PPh3)]BF4 3 showing a novel square-pyramidal intermediate with a weakly interacting oxygen in the apical position.
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Doi:10.1002/jhet.5570330329
(1996)Doi:10.1016/S0040-4020(97)00329-3
(1997)Doi:10.1021/ja01111a043
(1953)Doi:10.1021/jm960052s
(1996)Doi:10.1002/anie.202012400
(2021)Doi:10.1016/0960-894X(96)00289-2
(1996)
