Synthesis of the first stable carborane containing simple enol

DOI: 10.1007/BF01434241

Source and publish data:

Russian Chemical Bulletin p. 1490 - 1491 (1996)

Update date:2022-08-04

Topics:

Authors:

Zakharkin

Ol'shevskaya

Zhigareva

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Article abstract of DOI:10.1007/BF01434241

A carborane-containing stable simple enol - 1-(2-isopropyl-o-carboran-1-yl)-1-phenyl-2-mesityl-2-hydroxyethylene - has been synthesized. This enol does not isomerize to the starting ketone or keto-enol mixture even after prolonged heating in benzene in the presence of CF₃COOH.

Full text of DOI:10.1007/BF01434241

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Product name:B₁₀C₂H₁₀(C₃H₇)(CH(C₆H₅)COC₆H₂(CH₃)3)

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