Tetrahedron p. 11053 - 11062 (1996)
Update date:2022-08-04
Topics:
Szantay, Csaba
Kardos-Balogh, Zsuzsanna
Moldvai, Istvan
Szantay Jr., Csaba
Temesvari-Major, Eszter
Blasko, Gabor
Two different syntheses of Epibatidine (1) were designed and carried out using easily accessible reagents and convenient reaction conditions. The ring closure of the prochiral precursor 4 catalyzed by optically active α-phenyl-ethyl-amine gave the key intermediate 5 in over 80% ee from which the natural product (-)-1 has been prepared.
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