Journal of Organometallic Chemistry p. 325 - 334 (1996)
Update date:2022-08-04
Topics:
Tamao, Kohei
Asahara, Masahiro
Kawachi, Atsushi
Pseudo-pentacoordinate 1-(8-dimethylamino-1-naphthyl)-1-hydrodisilanes 1 and 2 and the tetracoordinate counterpart 3 have been prepared. In the presence of an Ni(0) complex as catalyst, 1 and 2 undergo degradation to generate a silylene species and a hydrosilane. The complex with Ni of the silylene species from 1 has been trapped with an excess of diphenylacetylene to give a pseudo-pentacoordinate silole 4. The X-ray structure of 4 indicates that this silole occupies two pseudo-equatorial positions. In contrast, the tetracoordinate hydrodisilane 3 undergoes hydrosilation without Si-Si bond cleavage.
View MoreContact:86-28-61993785
Address:No.70-13-21, North Section, Erhuan
Lyrin Industrial Corporation Limited
Contact:86-731-82571800
Address:Rm 2408,Asia Economy International Building,Shaoshan Road South,Yuhua District,Changsha,Hunan,China
Contact:0086-29-88315623
Address:S711, Innovation Bldg No.25 Gaoxin 1st Rd, Xian P.R of China 710075
Contact:86-512-69362780,69362785
Address:No.69 Weixin Road,Weiting Town,Suzhou Industrial Park
Nanjing Vincero International Trading Co.,Ltd
Contact:8618936897229
Address:NO.68, ZhuShan Road, JiangNing WanDa Plaza, Building E Room 1703
Doi:10.1021/om960406d
(1996)Doi:10.1016/0040-4039(96)01226-9
(1996)Doi:10.1016/S0040-4039(02)01033-X
(2002)Doi:10.1007/BF01164793
(1996)Doi:10.1016/j.tet.2013.04.039
(2013)Doi:10.1080/00304949609458576
(1996)