Journal of Organometallic Chemistry p. 325 - 334 (1996)
Update date:2022-08-04
Topics:
Tamao, Kohei
Asahara, Masahiro
Kawachi, Atsushi
Pseudo-pentacoordinate 1-(8-dimethylamino-1-naphthyl)-1-hydrodisilanes 1 and 2 and the tetracoordinate counterpart 3 have been prepared. In the presence of an Ni(0) complex as catalyst, 1 and 2 undergo degradation to generate a silylene species and a hydrosilane. The complex with Ni of the silylene species from 1 has been trapped with an excess of diphenylacetylene to give a pseudo-pentacoordinate silole 4. The X-ray structure of 4 indicates that this silole occupies two pseudo-equatorial positions. In contrast, the tetracoordinate hydrodisilane 3 undergoes hydrosilation without Si-Si bond cleavage.
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Doi:10.1021/om960406d
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(1996)