Efficient method for inversion of secondary alcohols by reaction of chloromethanesulfonates with cesium acetate

DOI: 10.1016/0040-4039(96)01333-0

Source and publish data:

Tetrahedron Letters p. 6145 - 6148 (1996)

Update date:2022-08-05

Topics:

Authors:

Shimizu, Takeshi

Hiranuma, Sayoko

Nakata, Tadashi

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/0040-4039(96)01333-0

Inversion of a variety of secondary alcohols using the (chloromethylsulfonyl)oxy group as a favorable leaving group with cesium acetate in the presence of 18-crown-6 has been performed to give the inverted acetates in high yields.

Full text of DOI:10.1016/0040-4039(96)01333-0

Products guided by the article

Product name:(2R,3S)-1,5-Bis-(tert-butyl-diphenyl-silanyloxy)-2-methyl-pentan-3-ol

Cas No:182243-55-6

R&D Labs maybe for 182243-55-6

Jinan Trio PharmaTech Co., Ltd

Contact:86-531-88811783；+(0)13153010282

Address:2766 Yingxiu Road, Jinan High-Tech Zone, China
Jinan Baozhao Pharmaceutical Co., Ltd

Contact:0086-531-86397156 82371858 82371868

Address:Huaneng Road, Jinan, Shandong ,China
Allicon Pharmaceuticals,Inc.

Contact:+86-519-86339586，13584329896

Address:Changzhou Scientific and Education Park
Suzhou Time-chem Technologies Co., Ltd.

Contact:0512-63983931/68086856

Address:No. 1326 of Binhe Road, New District, Suzhou, Jiangsu, P. R. China
Huaian Double Win Chemicals Co.,Ltd.

Contact:+86-13511538872

Address:Blk 43,Greenland Century Town,Huaian District, Huaian City,Jiangsu Province,China

Relevant to this article

Enantiomerically pure α-fluoroalkyl-α-amino acids: Synthesis of (R)-α-difluoromethyl-alanine and (S)-α-difluoromethyl-serine

Doi:10.1016/0957-4166(96)00287-X
(1996)
Doi:10.1021/ja00884a018
(1963)
Svnthesis and X-ray Crystal Structure of the First Mononuclear with a (S,N,N,O)

Doi:10.1002/cber.19961291007
(1996)
Synthesis of chemically and functionally diverse scaffolds from pentaerythritol

Doi:10.1139/v96-191
(1996)
Engineered cytochrome c-Catalyzed lactone-carbene B-H insertion

Doi:10.1055/s-0037-1611662
(2019)
Synthesis of chiral triamines and diamines from amino acids

Doi:10.1055/s-1996-4358
(1996)

Article Doi