Efficient method for inversion of secondary alcohols by reaction of chloromethanesulfonates with cesium acetate

DOI: 10.1016/0040-4039(96)01333-0

Source and publish data:

Tetrahedron Letters p. 6145 - 6148 (1996)

Update date:2022-08-05

Topics:

Authors:

Shimizu, Takeshi

Hiranuma, Sayoko

Nakata, Tadashi

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/0040-4039(96)01333-0

Inversion of a variety of secondary alcohols using the (chloromethylsulfonyl)oxy group as a favorable leaving group with cesium acetate in the presence of 18-crown-6 has been performed to give the inverted acetates in high yields.

Full text of DOI:10.1016/0040-4039(96)01333-0

Products guided by the article

Product name:(2R,3S)-1,5-Bis-(tert-butyl-diphenyl-silanyloxy)-2-methyl-pentan-3-ol

Cas No:182243-55-6

R&D Labs maybe for 182243-55-6

Hebei Kangtai Pharmaceutical Co.,Ltd

Contact:+86-0317-3512963

Address:Wugang Road,Mengcun of Cangzhou City,Hebei Province ,China
Linyi VIHO Chemical Co.,Ltd

Contact:86-15588110016

Address:LINYI CITY,SHANDONG PROVINCE,CHINA
Zibo Linzi Darong Fine Chemical Co., Ltd(expird)

Contact:86-532-67773200; 15689126900

Address:Qidu town,Linzi district,Zibo city,Shandong province,China
Hangzhou Share Chemical Co., Ltd(expird)

Contact:+86-57187093700

Address:Hang Xing Road
feixia327@163.com

Contact:--

Address:80G, No.1 Building, Guodu Development Mansion, No. 182 Zhaohui Road, Hangzhou City, Zhejiang Province,China.

Relevant to this article

Enantiomerically pure α-fluoroalkyl-α-amino acids: Synthesis of (R)-α-difluoromethyl-alanine and (S)-α-difluoromethyl-serine

Doi:10.1016/0957-4166(96)00287-X
(1996)
Doi:10.1021/ja00884a018
(1963)
Svnthesis and X-ray Crystal Structure of the First Mononuclear with a (S,N,N,O)

Doi:10.1002/cber.19961291007
(1996)
Synthesis of chemically and functionally diverse scaffolds from pentaerythritol

Doi:10.1139/v96-191
(1996)
Engineered cytochrome c-Catalyzed lactone-carbene B-H insertion

Doi:10.1055/s-0037-1611662
(2019)
Synthesis of chiral triamines and diamines from amino acids

Doi:10.1055/s-1996-4358
(1996)

Article Doi