Efficient method for inversion of secondary alcohols by reaction of chloromethanesulfonates with cesium acetate

DOI: 10.1016/0040-4039(96)01333-0

Source and publish data:

Tetrahedron Letters p. 6145 - 6148 (1996)

Update date:2022-08-05

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Authors:

Shimizu, Takeshi

Hiranuma, Sayoko

Nakata, Tadashi

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Article abstract of DOI:10.1016/0040-4039(96)01333-0

Inversion of a variety of secondary alcohols using the (chloromethylsulfonyl)oxy group as a favorable leaving group with cesium acetate in the presence of 18-crown-6 has been performed to give the inverted acetates in high yields.

Full text of DOI:10.1016/0040-4039(96)01333-0

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