Chemical Communications p. 2043 - 2044 (1996)
Update date:2022-08-04
Topics:
Lang, Heinrich
Koehler, Katrin
Zsolnai, Laszlo
Linearity directed donor-stabilized organogold(I) compounds react with the 3-titanopenta-1,4-diyne [(η5-C5H4SiMe3) 2Ti(C≡CSiMe3)2]T 1 to afford complexes 1·Au(η1-R) [R = Me 3a, C6H2(CF3)3-2,4,6 3b, C≡CSiMe3 3c] in which the gold(I) centre possesses a trigonal-planar environment formed by two η2-coordinated alkyne units and a η1-bonded organic group R; the X-ray structure analysis of [{(η5-C5H4SiMe3) 2Ti(C≡CSiMe3)2} Au(η1-C6H2(CF3) 2-2,4,6}] 3b is reported.
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Doi:10.1080/00397919608003828
(1996)Doi:10.1007/BF01172546
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(1965)Doi:10.1007/BF00807034
(1996)Doi:10.1039/c4ra15919e
(2015)Doi:10.1002/anie.199623531
(1996)
