Angewandte Chemie - International Edition in English p. 2353 - 2355 (1996)
Update date:2022-08-04
Topics:
Menage
Galey
Hussler
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An excellent functionalized enzyme model for the active site of methane monooxygenase and ribonucleotide reductase is represented by the μ-acetato- and μ-oxo-bridged diiron complex 1. Reaction with H2O2 or O2 in the presence of ascorbate leads to hydroxylation of one phenyl ring to a phenol. This then coordinates to the metal center with formation of a mononuclear complex.
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