Suzaki-coupling of Cp*Ru(para-C6M4Br2) with phenyl boronic acid: A model recation for the synthesis of organometallic polymers

DOI: 10.1002/cber.19961291103

Source and publish data:

Chemische Berichte p. 1323 - 1325 (1996)

Update date:2022-08-03

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Authors:

Harre, Kathrin

Enkelmann, Volker

Schulze, Margit

Bunz, Uwe H. F.

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Article abstract of DOI:10.1002/cber.19961291103

The synthesis of a terphenyi derivative complexed by the cationic moiety Cp*Ru⁺ by Suzuki coupiing of [Cp*Ru(BrC₆H₄-Br)]OTf with phenyl boronic acid under catalysis of Pd(PPh₃)₄ in a DME-water mixture at 85 °C in quantitative yield is reported. The stable coupling product 3 was characterized by X-ray crystal structure analysis. VCH Verlagsgesellschaft mbH, 1996.

Full text of DOI:10.1002/cber.19961291103

Products guided by the article

Product name:Ru(C₆H₅C₆H₄C₆H₅)(C₅(CH₃)5)⁽¹⁺⁾*O₃SCF₃^(1-) = [Ru(C₆H₅C₆H₄C₆H₅)(C₅(CH₃)5)]O₃SCF₃

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