Tetrahedron Asymmetry p. 2585 - 2593 (1996)
Update date:2022-08-03
Topics:
Hoarau, Sylvie
Fauchere, Jean Luc
Pappalardo, Louis
Roumestant, Marie Louise
Viallefont, Philippe
An asymmetric synthesis of cis- and trans-5-hydroxy-(D)-pipecolic acid, starting from glycinate Schiff bases is described. The approach involves the stereoselective alkylation to generate an unsaturated side chain which on cyclisation leads to the desired trans- or cis-5-hydroxy-(D)-pipecolic acid.
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