Synthesis of enantiomerically pure (2R,5S)- and (2R,5R)-5-hydroxypipecolic acid from glycinate Schiff bases

DOI: 10.1016/0957-4166(96)00332-1

Source and publish data:

Tetrahedron Asymmetry p. 2585 - 2593 (1996)

Update date:2022-08-03

Topics:

Authors:

Hoarau, Sylvie

Fauchere, Jean Luc

Pappalardo, Louis

Roumestant, Marie Louise

Viallefont, Philippe

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/0957-4166(96)00332-1

An asymmetric synthesis of cis- and trans-5-hydroxy-(D)-pipecolic acid, starting from glycinate Schiff bases is described. The approach involves the stereoselective alkylation to generate an unsaturated side chain which on cyclisation leads to the desired trans- or cis-5-hydroxy-(D)-pipecolic acid.

Full text of DOI:10.1016/0957-4166(96)00332-1

Products guided by the article

Product name:5-Hexenoic acid, 2-[[(phenylmethoxy)carbonyl]amino]-, 1,1-dimethylethyl ester, (R)-

Cas No:183882-53-3

R&D Labs maybe for 183882-53-3

KAIYUAN CHEMICAL COMPANY LIMITED.

website:http://www.kaiyuanchem.com

Contact:+86-22-59891255/66/77

Address:B-2205, Kuangshi International Building, Yingbin Road, XiangLuo Bay Business District, Binhai New area, Tianjin, China.
Dalian Join King Biochemical Tech. Co., Ltd.

Contact:0411 39216206

Address:814 First State Blvd
Second Pharma Co., Ltd

Contact:+86-575-82733999 0575-82732999

Address:hangzhou gulf fine chemical zone,shangyu city,zhejiang province
enantiotech corporation ltd

Contact:+86-0760-85282375

Address:zhongjing road,zhongshan torch hi-tech industrial development zone
Shanghai SMEC Trading Co., Ltd.

website:http://www.shanghaismec.com

Contact:+86-21-68811293

Address:ROOM 1101,NO.800 SHANGCHENG RD,SHANGHAI,CHINA

Relevant to this article

Doi:10.1021/acs.orglett.8b02489
(2018)
Ru₃(CO)₁₂ in Acidic Media. Intermediates of the Acid-Cocatalyzed Water-Gas Shift Reaction (WGSR)

Doi:10.1021/ic960630v
(1996)
Syntheses and first crystal structures of rhenium complexes derived from ω-functionalized fatty acids as model compounds of technetium tracers for myocardial metabolism imaging

Doi:10.1002/1099-0682(200205)2002:5<1219::AID-EJIC1219>3.0.CO;2-N
(2002)
Colloid and nanosized catalysts in organic synthesis: IX hydrogenation of enamines with hydrogen at atmospheric pressure

Doi:10.1134/S1070363214110036
(2014)
Synthesis of novel 6-amido-6-deoxy-L-galactose derivatives as sialyl Lewis X mimetics

Doi:10.1016/S0968-0896(96)00236-2
(1997)
Semisyntheses, X-Ray Crystal Structures and Tubulin-Binding Properties of 7-Oxodeacetamidocolchicine and 7-Oxodeacetamidoisocolchicine

Doi:10.1071/CH9921577
(1992)

Article Doi