The effect of polar substituents on the conformation and stereochemistry of enolate radicals

DOI: 10.1016/S0040-4039(00)73805-6

Source and publish data:

Tetrahedron Letters p. 5885 - 5888 (1993)

Update date:2022-08-05

Topics:

Authors:

Giese Giese

Damm Damm

Wetterich

Zeitz Zeitz

Rancourt

Guindon Guindon

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/S0040-4039(00)73805-6

ESR measurements and AM1 calculations show that ester substituted radicals 2 and 6 prefer conformation A as a result of allylic strain effects. But dipolar repulsion between substituents X and CO₂Et In 2 and 6 has a pronounced effect on the con

Full text of DOI:10.1016/S0040-4039(00)73805-6

Products guided by the article

Product name:1-(tert-butyldiphenylsilyloxy)-2,4,6-trimethylnonane-3,5,7-trione

Cas No:184851-61-4

R&D Labs maybe for 184851-61-4

Anhui Eapearl Chemical Co., Ltd.

Contact:86-562-5858458

Address:358 South Huaihe Road
Shijiazhuang City Xiehe Pharmaceutical Co., Ltd

Contact:+86-311-80817929

Address:Shangzhuang,Shijiazhuang,China
Linyi VIHO Chemical Co.,Ltd

Contact:86-15588110016

Address:LINYI CITY,SHANDONG PROVINCE,CHINA
Guangzhou Chemical Reagent Factory

Contact:+86-20-8435 9820 or 8435 7345

Address:Southern Guangzhou, Guangdong, China
Kraeber & Co GmbH

Contact:+49-4101-3053-0

Address:Waldhofstrasse 14 ,25474 Ellerbek Germany

Relevant to this article

Spiro[1,2,4-benzotriazine-3(4H),4′-(1′-substituted)piperidines] and related compounds as ligands for sigma receptors

Doi:10.1016/S0014-827X(02)01293-4
(2003)
A practical method for the synthesis of D- or L-α-amino acids by the alkylation of (+)- or (-)-pseudoephedrine glycinamide

Doi:10.1021/ja00137a034
(1995)
Farnesyl and geranylgeranyl pyrophosphate analogs incorporating benzoylbenzyl ethers: Synthesis and inhibition of yeast protein farnesyltransferase

Doi:10.1016/S0040-4039(96)02066-7
(1996)
Dual Catalytic Decarboxylative Allylations of α-Amino Acids and Their Divergent Mechanisms

Doi:10.1002/chem.201503644
(2015)
P-coumaroylated syringyl units in maize lignin: Implications for β- ether cleavage by thioacidolysis

Doi:10.1016/S0031-9422(96)00431-1
(1996)
Doi:10.1039/jr9650003645
(1965)

Article Doi