The effect of polar substituents on the conformation and stereochemistry of enolate radicals

DOI: 10.1016/S0040-4039(00)73805-6

Source and publish data:

Tetrahedron Letters p. 5885 - 5888 (1993)

Update date:2022-08-05

Topics:

Authors:

Giese Giese

Damm Damm

Wetterich

Zeitz Zeitz

Rancourt

Guindon Guindon

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Article abstract of DOI:10.1016/S0040-4039(00)73805-6

ESR measurements and AM1 calculations show that ester substituted radicals 2 and 6 prefer conformation A as a result of allylic strain effects. But dipolar repulsion between substituents X and CO₂Et In 2 and 6 has a pronounced effect on the con

Full text of DOI:10.1016/S0040-4039(00)73805-6

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