Polyhedron p. 133 - 141 (1997)
Update date:2022-08-03
Topics:
Arnold, Deirdre I.
Cotton, F. Albert
Maloney, David J.
Matonic, John H.
Murillo, Carlos A.
A series of compounds of the type [MCl2(amidine)2]n, M = Mn, Co and Ni, has been prepared in high purity and yield by solubilizing otherwise insoluble metal chlorides in the presence of neutral amidines in refluxing toluene. As crystalline solids, they are stable in air for several days. The compounds are excellent starting materials for the formation of dinuclear compounds. A complete chemical and structural characterization is provided for the penta-coordinated dimanganese compound [MnCl2(HDPhF)2]2, I (DPhF = diphenylformamidinato), the mononuclear compounds CoCl2(HDPhBz)2, II (DPhBz = diphenylbenzamidinato), and NiCl2(HDTolF)2, III (DTolF = di-p-tolylformamidinato). The HDPhF analogue of III reacts with a strong base to give the dinuclear species Ni2(DPhF)4 (IV), the structure of which is also reported here. Copyright
View MoreContact:+86-0311-84455288-844
Address:Mayu Industrial Park, Jinzhou, Hebei, China.
Zhejiang Allied Chemical Co.,Ltd
Contact:18967038207
Address:Area A-30, High-tech Industrial Park, Quzhou, Zhejiang, China.
website:http://www.josunpharma.com
Contact:+86-311-80715268 80766839
Address:No.39, Zhaiying Street, Shijaizhuang,Hebei,China
Beijing Green Guardee Technology CO,.LTD
Contact:+86-10-69706062
Address:F2 BLdj,5 No.37 Chaoqian Road
Hebei DaPeng Pharm & Chem Co., Ltd.
Contact:86-317-7298678,0576-88861898 88861908
Address:West Songmen Village, East Songmen Town, Wuqiao, Cangzhou, Hebei ,China
Doi:10.1016/S0960-894X(96)00487-8
(1996)Doi:10.1021/ja9635037
(1997)Doi:10.1271/bbb.80903
(2009)Doi:10.1021/ja01861a019
(1940)Doi:10.1016/S0040-4039(98)00365-7
(1998)Doi:10.1039/DT9960004379
(1996)
