Tetrahedron Letters p. 8319 - 8322 (1997)
Update date:2022-08-03
Topics:
Iwashima, Makoto
Watanabe, Kinzo
Iguchi, Kazuo
Two new marine prostanoids, preclavulone lactones I (1) and II (2) were isolated from the Okinawan soft coral, Clavularia viridis. Their structures were determined based on spectroscopic analysis and chemical synthesis from (S)-malic acid. Preclavulone lactones with side chains having absolute configurations opposite to those of mammalian prostanoids could be recognized as key intermediates in biosynthesis of clavulones.
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