Formal synthesis of (-)-calicheamicinone and of (+)-calicheamicinone

DOI: 10.1039/CC9960002543

Source and publish data:

Chemical Communications p. 2543 - 2544 (1996)

Update date:2022-08-04

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Authors:

Clive, Derrick L. J.

Selvakumar, Natesan

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Article abstract of DOI:10.1039/CC9960002543

An asymmetric Diels-Alder reaction between ketene acetal 2 and the 3-nitropropenoate 10, derived from (-)-8-phenyl-menthol, affords the optically pure adduct 15, which can be converted into either enantiomer of calicheamicinone 1.

Full text of DOI:10.1039/CC9960002543

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