Journal of the Chemical Society, Dalton Transactions p. 4227 - 4232 (1996)
Update date:2022-08-05
Topics:
Yam, Vivian Wing-Wah
Choi, Sam Wing-Kin
A series of alkynylgold(I) phosphine complexes with various bridging phosphines and acetylide ligands have been synthesized. All complexes have been shown to exhibit rich photophysical and photochemical behaviour. A systematic comparative study on their spectroscopy and photophysics has been attempted. The complexes undergo facile electron-transfer reactions with pyridinium electron acceptors. The redox nature of the quenching reactions has been established by time-resolved transient absorption spectroscopy.
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Doi:10.1002/hlca.19800630425
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