Tetrahedron Letters p. 5793 - 5796 (1988)
Update date:2022-07-31
Topics: Reduction Triethylsilane Experimental boron trifluoride studies
Smonou, Ioulia
Orfanopoulos, Michael
The kinetic hydrogen-deuterium isotope effects and the stereochemistry of the deoxygenation of 1-phenylethanol with boron trifluoride and triethylsilane have been studied.The results are consistent with a mechanism that involves of the formation of the phenethyl cation in a rate determining step and its fast reduction with triethylsilane.
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