A cationic zinc hydride cluster stabilized by an N-heterocyclic carbene: Synthesis, reactivity, and hydrosilylation catalysis

DOI: 10.1002/anie.201408346

Source and publish data:

Angewandte Chemie - International Edition p. 13273 - 13277 (2014)

Update date:2022-08-04

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Authors:

Rit, Arnab

Zanardi, Alessandro

Spaniol, Thomas P.

Maron, Laurent

Okuda, Jun

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Article abstract of DOI:10.1002/anie.201408346

The trinuclear cationic zinc hydride cluster [(IMes)₃Zn₃H₄ (THF)](BPh₄)₂ (1) was obtained either by protonation of the neutral zinc dihydride [(IMes)ZnH₂]₂ with a Bronsted acid o

Full text of DOI:10.1002/anie.201408346

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