Organic Letters p. 6724 - 6728 (2021)
Update date:2022-08-02
Topics:
Chen, Xing
Li, Mengke
Liu, Zhipeng
Yang, Can
Xie, Haisheng
Hu, Xinwei
Su, Shi-Jian
Jiang, Huanfeng
Zeng, Wei
An unprecedented Pd/Rh cooperatively catalyzed arylalkynylation of alkynylsilanes was developed to merge an alkynylidene moiety with benzosilacycle. These silaarenes possess a particular aggregation-induced emission behavior. Mechanistic investigations demonstrate that the relay trimetallic transmetalation plays a pivotal role in governing this transformation.
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