Heterocycles p. 919 - 927 (1998)
Update date:2022-07-29
Topics:
Cho, Hidetsura
Murakami, Kengo
Nakanishi, Hiroyuki
Isoshima, Hirotaka
Hayakawa, Kazuhide
Uchida, Itsuo
5,6,7,8-Tetrahydrothieno[3,2-b]azepine,5,6,7,8-tetrahydro-1H-furo[3,2-b] azepine, and 1,4,5,6,7,8-hexahydropyrrolo[3,2-b]azepine were synthesized by the ring expansion reaction of heterocyclic fused cyclohexanone oximes with diisobutylaluminum hydride (DIBAH). The mechanism of the reaction was different from that of Beckmann rearrangement.
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