Tetrahedron Letters p. 547 - 550 (1997)
Update date:2022-08-02
Topics:
Kojima, Satoshi
Akiba, Kin-Ya
The reaction of a β-hydroxyspirophosphorane (4) bearing Martin ligands with base was found to give a hexacoordinate phosphate (isomer 1), which eventually isomerized to another phosphate (isomer 2). Kinetic examination of the stereomutation process implied that it involved P-O bond heterolysis as the rate determining step. This was assumed to be followed by pseudorotation and P-O bond formation.
View MoreContact:+86-731-84427351
Address:154 JIANXIANG SOUTH ROAD
Contact:17316303296
Address:240 Amboy Ave
Tianjin Boron PharmaTech Co.,Ltd.(expird)
Contact:86-022-59845187
Address:B9-401, Tianda Science Park,No.80,4th Avenue,TEDA,Tianjin, China
Hangzhou Donglou Bio-nutrient Co., Ltd.
Contact:+86-571-82225795,13967112289
Address:Louta Town, Xiaoshan,Hangzhou,Zhejiang
Yancheng Smiling Imp & Exp Co., Ltd.
Contact:+86-515-83173586
Address:Rm1207, BLD#03, Phoenix Plaza, Juheng Road, Yancheng, Jiangsu, P.R. China
Doi:10.1007/s10637-009-9360-3
(2011)Doi:10.1055/s-2006-939047
(2006)Doi:10.1002/1522-2675(200208)85:8<2328::AID-HLCA2328>3.0.CO;2-X
(2002)Doi:10.1134/S0036024409040232
(2009)Doi:10.1021/ja028663z
(2002)Doi:10.1021/jm020173u
(2002)