Tetrahedron Letters p. 547 - 550 (1997)
Update date:2022-08-02
Topics:
Kojima, Satoshi
Akiba, Kin-Ya
The reaction of a β-hydroxyspirophosphorane (4) bearing Martin ligands with base was found to give a hexacoordinate phosphate (isomer 1), which eventually isomerized to another phosphate (isomer 2). Kinetic examination of the stereomutation process implied that it involved P-O bond heterolysis as the rate determining step. This was assumed to be followed by pseudorotation and P-O bond formation.
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