Journal of the American Chemical Society p. 4130 - 4135 (1997)
Update date:2022-08-03
Topics:
Sha, Chin-Kang
Chiu, Rei-Torng
Yang, Cheng-Fen
Yao, Nai-Tung
Tseng, Wei-Hong
Liao, Fen-Ling
Wang, Sue-Lein
An efficient total synthesis of enantiomerically pure (-)-dendrobine (1) is accomplished based on an α-carbonyl radical cyclization reaction. (S)- carvotanacetone (6) was convened to bicyclic acetal-enone 4 in five steps. Cul-mediated conjugate addition o
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Doi:10.1021/jo00128a035
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