Tetrahedron p. 2653 - 2666 (1997)
Update date:2022-07-29
Topics:
Pakulski, Zbigniew
Zamojski, Aleksander
Propargylation of pentofuranose aldehydes by treatment with propargyl bromide in the presence of zinc dust yielded homopropargylic alcohols with a good isolated yield and, in many cases, excellent anti/syn selectivity. Catalytic hydrogenation of the triple bond afforded homoallylic alcohols, valuable substrates for the synthesis of 6-deoxyheptoses. Direct ozonolysis of the triple bond yielded uronic acid esters.
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Doi:10.1021/jm970019l
(1997)Doi:10.1021/jm970157a
(1997)Doi:10.1016/S0040-4020(97)00445-6
(1997)Doi:10.1139/v68-132
(1968)Doi:10.1016/S0022-1139(96)03536-1
(1997)Doi:10.1016/S0040-4020(97)90401-4
(1997)