The synthesis of sultines from δ-hydroxy sulfoxides revisited

DOI: 10.1016/S0040-4039(97)00093-2

Source and publish data:

Tetrahedron Letters p. 1337 - 1340 (1997)

Update date:2022-08-05

Topics:

Authors:

Connolly, Terrence J.

Durst, Tony

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/S0040-4039(97)00093-2

A re-examination of a previously thought general synthesis of sultines from δ-hydroxy sulfoxides is shown to be more complicated than originally believed. The products obtained can be α,α'-dihaloxylenes or δ-halosulfones. The results are best interpreted based on carbocation stability of the key oxo-sulfoxonium salt intermediate.

Full text of DOI:10.1016/S0040-4039(97)00093-2

Products guided by the article

Product name:1H-Indole-4-carboxylic acid, 3-[(phenylmethyl)thio]-, methyl ester

Cas No:188656-65-7

R&D Labs maybe for 188656-65-7

Hangzhou Yanshan Chemical Co.,Ltd.

Contact:86-571- 87698076

Address:Room 1001, #1 Building, Zhongtian MCC, No.2 Youzhinong, Wenyi West Road, Xihu District, Hangzhou, China
Changzhou Hopschain Chemical Co.,Ltd

website:http://www.hopschem.cn/products.html

Contact:86-519-85528066

Address:Room 710, Unit A, Xingbei Development Mansion, Tongjiang Road, Changzhou City,213000, China
Zhongshan Haihong Medicine Co., Ltd.

Contact:86-0760-86925778 （0）18824993998

Address:A7 building,lianyuan road Torch Hi-tech Industrial Development Zone
Wuxi Forest Biological Co.,Ltd

Contact:+86-510-81602300

Address:Room 317,Building D, No.159 middle Chengjiang Road,Jiangyin Wuxi city.
ZHEJIANG JIANYE CHEMICAL CO.,LTD.

Contact:86-571-64149273,64149234

Address:No. 48, Fuxi Road, Meicheng Town

Relevant to this article

Concerning the preparation of 7-amino-cephalosporanic acid

Doi:10.1002/hlca.19680510513
(1968)
A case of C-H activation (ortho metalation) which is reversible at 25 °C

Doi:10.1021/om9607107
(1997)
Synthesis of 2-substituted-1H-pyrrolo[2,3-b]pyridines: Preparation of 7-azaolivacine analogue and 7-azaindolopyridopyrimidine derivatives

Doi:10.1016/S0040-4020(97)00107-5
(1997)
Conformationally constrained [p-(ω-aminoalkyl)phenacetyl]-L-seryl-L- lysyl dipeptide amides as potent peptidomimetic inhibitors of Candida albicans and human myristoyl-CoA:protein N-myristoyl transferase

Doi:10.1021/jm9608671
(1997)
Dipeptides bearing nucleobases for the synthesis of novel peptide nucleic acids

Doi:10.1039/a603699f
(1997)
Prins desymmetrization of a C₂-symmetric diol: Application to the synthesis of 17-deoxyroflamycoin

Doi:10.1021/jo970380f
(1997)

Article Doi