Journal of the American Chemical Society p. 712 - 714 (1989)
Update date:2022-08-02
Topics:
LaVilla, Joseph A.
Goodman, Joshua L.
The heats of formation and reaction of several singlet carbenes are determined by time-resolved photoacoustic calorimetry.The most selective and least reactive carbene examined, methoxychlorocarbene, is the most stable and reacts least exothermically with CH3OH.The phenylhalocarbenes have similar stabilities and reaction exothermicities with CH3OH.The experimental carbene heats of formation in solution are systematically lower and the stabilization energies higher than the values from MNDO calculations.This potentially result from (i) solvation of the carbene, (ii) an unresolved reaction volume change, or (iii) incorrect MNDO calculated carbene and diaziridine enthalpies.
View MoreJiaxing Trustworthy Import And Export Co.,Ltd
Contact:+86-573-82030555
Address:Room 1202, Unit B, Charming plaza,No.1558 East Zhongshan Road , Jiaxing City, Zhejiang Province, China.
NINGBO YINZHOU PRECISE COLOR CO.,LTD.
Contact:86-574-88139809 86-574-83033159
Address:Qiming Road,Yinzhou,Ningbo,China
Hunan Shineway Enterprise Co., Ltd.
Contact:+86-731-86303875
Address:118, Huanghua International Airport Road, Huanghua Town, Changsha, Hunan 410137, China
Jinan YouCheng Pharmatech Co.,Ltd
Contact:+86-18653163205
Address:No.750, Shunhua Road, University Science Park, High-tech Zone, Jinan City
Taizhou YOJOY Chemical Co., Ltd.
Contact:13857143241
Address:Yangfu Industrial Park, Xianju, Zhejiang, P. R. China
Doi:10.1016/S0008-6215(97)00013-X
(1997)Doi:10.1021/om970096e
(1997)Doi:10.1016/S0957-4166(97)00042-6
(1997)Doi:10.1016/S0040-4039(01)87681-4
(1969)Doi:10.1007/s10562-019-02675-0
(2019)Doi:10.1007/s11094-019-01968-3
(2019)
