Journal of Organometallic Chemistry p. 39 - 54 (1986)
Update date:2022-08-04
Topics:
Roesch, Wolfgang
Vogelbacher, Uwe
Allspach, Thomas
Regitz, Manfred
The phosphaalkenes are derived from tris(trimethylsilyl)phosphine and acid chlorides, with acylphosphines considered as intermediates of the reaction.Sodium hydroxide-catalysed elimination of hexamethyl disiloxane (120-160 deg C) at the phosphaalkenes yields the hitherto unknown phosphaalkynes.These are chemically characterised by <3 + 2>-cycloaddition reactions with diazomethane ( -> 1,2,4-diazaphospholes), methyl azide ( -> 1,2,3,4-triazaphospholes) and benzonitriloxide (1,2,4-oxazaphospholes).
View MoreShanghai Taibao Pharmaceutical Technology Co., Ltd(expird)
Contact:021-52217366
Address:shanghai
Shanghai shibo Chemical Co., Ltd
Contact:+86-021-60753516
Address:688 Qiushi Road, Jinshan High-tech Park, Shanghai, China,201512
Ningbo Hi-tech Zone Nice-Synth Chemical Industry Ltd.
Contact:+86-(574)-81110986
Address:No. 1210, Building 3, Wante Business Centre, Hi-tech Zone, Ningbo
Contact:+852-8198 2399
Address:9E, Leapont Industrial Building, 18-28 Wo Liu Hang Road, Shatin, New Territories, Hong Kong
Xi'an yuanfar international trade company
website:https://www.yuanfarchemical.com
Contact:86-029-88745613 ext 828
Address:Floor19th ,B Building, Oak Block,No.36 South Fenghui Road, Dev. Zone of High-Tech Ind.,Xi’an, China
Doi:10.1246/cl.1997.419
(1997)Doi:10.1016/j.tet.2012.04.095
(2012)Doi:10.1021/ic961265a
(1997)Doi:10.1021/jo00324a048
(1981)Doi:10.1039/a608524e
(1997)Doi:10.1002/hc.10078
(2002)
