The cathodic cleavage of the S-P bond. Synthesis and electrochemical behaviour of sulfonamide phosphorus analogues

DOI: 10.1016/S0040-4039(97)00728-4

Source and publish data:

Tetrahedron Letters p. 3735 - 3738 (1997)

Update date:2022-08-05

Topics:

Authors:

Pilard, Jean-Francois

Simonet, Jacques

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Article abstract of DOI:10.1016/S0040-4039(97)00728-4

P-diphenylarylsulfophosphamides can be obtained by condensation of Ph₂PLi on various arylsulfonyl chlorides. These sulfonamide phosphorus analogues exhibit facile cathodic cleavage reaction yielding, after quenching, diphenylphosphinic acid and arylsulfide.

Full text of DOI:10.1016/S0040-4039(97)00728-4

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