Bryostatin: A novel asymmetric synthesis of the C27-C34 fragment starting from (R)-carvone as chiral template

DOI: 10.1016/S0957-4166(97)00170-5

Source and publish data:

Tetrahedron Asymmetry p. 1721 - 1724 (1997)

Update date:2022-08-03

Topics:

Authors:

De Brabander

Kulkarni

Garcia-Lopez

Vandewalle

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/S0957-4166(97)00170-5

(R)-Carvone is a suitable chiral template for the synthesis of differently protected (4S,6R,7R)-trihydroxy-1-octyne derivatives, the C₂₇-C₃₄ fragment of bryostatins. Also other potentially interesting chiral building blocks are described.

Full text of DOI:10.1016/S0957-4166(97)00170-5

Products guided by the article

Product name:(2R,3R,5R)-5-Acetyl-3-(tert-butyl-dimethyl-silanyloxy)-2-methyl-cyclohexanone

Cas No:191410-01-2

R&D Labs maybe for 191410-01-2

TAIXING BEST NEW MATERIALS CO., LTD

Contact:0523-87998158;

Address:No.18 Zhonggang Road，Taixing City ，Jiangsu , China
NEW FORTUNE INDUSTRIAL CO.,LTD.

website:http://newfortune.lookchem.com/

Contact:+86-25-8645-9456

Address:C4-105 GREEN ISLAND FLOWER TOWN
Reliable Pharma Technology (Shanghai) Co., Ltd.

Contact:0086-21-67676847-8008

Address:Lane 1500, No.68, Xinfei Road, Songjiang District, Shanghai, 201611, P.R.China.
Suns Chemical Sdn Bhd

Contact:0086 371 65711996

Address:Jalan 4/3, Kawasan Perindustrian Serendah, 48000 Rawang,
Shanghai TBBMed Co.,Ltd

website:http://www.tbbmed.com

Contact:86--21-50498136

Address:Room 6002, Building 7-1, No.160 Basheng Road,Pudong Area,Shanghai China

Relevant to this article

C,H bond activation of imino substituted heterocycles: Synthesis and crystal structure of [μ₂-η³-( R) N-CH₂-C=C-C(H) =C(H)-X ]Fe₂( CO) ₆ and the isomeric clusters [μ₂-η³-(R)N-CH₂-C=C-X-C(R′)=C(R″)]Fe₂(CO)₆

Doi:10.1016/S0022-328X(96)06824-6
(1997)
Synthesis of 2-aryltryptamines with palladium catalyzed cross-coupling of 2-bromotryptamines and arylboronic acids

Doi:10.1016/S0040-4039(97)00797-1
(1997)
Variable-Valent Re≡NAr Species. A Family of Re^VINAr Amide Complexes and Their Re^vNAr Imine Precursors Related by Oxygen Atom Transfer

Doi:10.1021/ic9701322
(1997)
Reaction of 4-oxochromene-3-carboxaldehydes with primary amides and benzotriazole or 1H-1,2,4-triazole

Doi:10.1135/cccc19970781
(1997)
Two isosteric fluorinated derivatives of the powerful glucosidase inhibitors, 1-deoxynojirimycin and 2,5-dideoxy-2,5-imino-D-mannitol: Syntheses and glycosidase-inhibitory activities of 1,2,5-trideoxy-2-fluoro-1,5-imino-D-glucitol and of 1,2,5-trideoxy-1-

Doi:10.1016/S0008-6215(97)00099-2
(1997)
Copper-promoted hydration and annulation of 2-fluorophenylacetylene derivatives: From alkynes to benzo[b]furans and benzo[b]thiophenes

Doi:10.3762/bjoc.10.305
(2014)

Article Doi