Tetrahedron Letters p. 3911 - 3914 (1997)
Update date:2022-08-05
Topics:
Suh, Young-Ger
Jung, Jae-Kyung
Kim, Soon-Ai
Shin, Dong-Yun
Min, Kyung-Hoon
A new variant of palladium-catalyzed stereoselective cyclization has been developed. This process provides an excellent 1,2-diastereocontrol of two new stereogenic centers as well as 1,3-asymmetric induction. In addition, desulfonylation of the cyclization product with retention of the initial stereochemistry and conversion of the desulfonylation product to the advanced carbaprostacyclin intermediate is described.
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